In situ Raman monitoring of [2+2] cycloaddition of pyridine substituted olefins induced by visible laser.
نویسندگان
چکیده
Visible laser induced [2+2] cycloaddition of solid-state pyridine substituted olefins into cyclobutane has been monitored by an in situ Raman technique. The laser power and wavelength can dramatically alter the reaction kinetics, as a prior melting process (heating from laser irradiation) is required for this [2+2] photoreaction.
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ورودعنوان ژورنال:
- Chemical communications
دوره 50 98 شماره
صفحات -
تاریخ انتشار 2014